Park, Ji-Hun Cho, Jae-Hyeon Lee, Nyun Jong Lee, Hyun-Jae Lee, Ju-Hyeon Lee, Geon-Ju Marlton, Frederick P. Suzuki, Motohiro Hinterstein, Manuel Oh, Yoon Seok Choi, Ji-Won Hwang, Geon-Tae Lee, Jun Hee Kim, Sanghoon Kim, Kee Hoon Jo, Wook 2024-11-07T01:30:14Z 2024-11-07T01:30:14Z 2024-11-06 2025-02 2199-160X https://pubs.kist.re.kr/handle/201004/150975 Albeit having great potential toward unprecedented type of applications such as magnetoelectric (ME) sensors and memories, practically useful single-phase multiferroics that show large coupling between ferromagnetism and ferroelectricity at ambient temperatures are still lacking. Here, the discovery of a new type of perovskite ferroelectrics (Pb,M)(Fe1/2Nb1/2)O-3 (M = Fe, Co, Ni) is reported with a magnetically-active metal ion introduced into a cuboctahedrally-coordinated Pb position, which exhibits enhanced ME coupling owing to the development of simultaneous soft-ferromagnetism and lone-pair ferroelectricity persistent above room temperature. These Pb-site engineered (Pb,M)(Fe1/2Nb1/2)O-3 perovskites exhibit a ME coupling coefficient of approximate to 40-60 ps m(-1), a saturated electric polarization of 14-17 mu C cm(-2) and a saturation magnetization of 0.15-0.3 mu (B) f.u(-1). X-ray absorption spectroscopy combined with first-principles calculations demonstrates that the induced ferromagnetism originates from the ferromagnetic superexchange interaction coming from approximate to 90 degrees bonding between the magnetic ions at the Pb site. The present discovery of the enhanced ME coupling in the Pb-site engineered perovskite ferroelectrics may provide unforeseen opportunities for applying conventional displacive ferroelectricity in the field of spintronics where ferromagnetism is essentially required. English Wiley-VCH Verlag Enhanced Coupling Between Soft Ferromagnetism and Displacive Ferroelectricity in the Pb-Site Modified PbFe1/2Nb1/2O3 Article 10.1002/aelm.202400370 1 Advanced Electronic Materials, v.11, no.2 Advanced Electronic Materials 11 2 Y scie scopus 001334673500001 2-s2.0-85206341342 Nanoscience & Nanotechnology Materials Science, Multidisciplinary Physics, Applied Science & Technology - Other Topics Materials Science Physics Article SUPEREXCHANGE INTERACTION MULTIFERROICS EXCHANGE ENERGY ferroelectricity/ferroelectric oxides ferromagnetism/ferromagnetic oxides magnetoelectric coupling multiferroics superexchange interaction