Nersisyan, Hayk Jeong, Junmo Suh, Hoyoung Lee, Jong Hyeon 2024-12-06T10:00:47Z 2024-12-06T10:00:47Z 2024-12-06 2025-01 https://pubs.kist.re.kr/handle/201004/151312 This study presents an efficient low-temperature process for synthesizing Mo nano- and microspheres for various applications. The synthesis process involves the preparation of a MoO3 + kZn mixture with an excess of zinc (Zn > 3) and processing to temperatures between 500 and 850 degrees C in an argon atmosphere. The growth kinetics of Mo particles are determined by analyzing the relationship between sphere diameter and processing time. Molybdenum nano- and microspheres are applied as electrocatalysts for the hydrogen evolution reaction (HER) and high electrocatalytic activity, including low overpotential (170-206 mV) and Tafel slope (40-50 mV dec(-1)) are recorded in 0.5 M H2SO4 electrolyte. DFT calculation provides adsorption Gibbs free energy for (001), (110), and (211) surfaces of Mo and charge density plots on pure Mo and Mo-O surfaces. As for vacuum-distilled Zn, its microstructure is also studied for its reuse and to assess its potential for additive manufacturing. English ROYAL SOC CHEMISTRY Thermochemical synthesis of Mo nano/microspheres: growth kinetics, electrocatalytic hydrogen evolution, and DFT insights Article 10.1039/d4qm00814f 1 Materials Chemistry Frontiers, v.9, no.1, pp.147 - 160 Materials Chemistry Frontiers 9 1 147 160 N scie scopus 001361011000001 2-s2.0-85209766141 Chemistry, Multidisciplinary Materials Science, Multidisciplinary Chemistry Materials Science Article COMBUSTION SYNTHESIS MOLYBDENUM REDUCTION ZINC NANOPOWDERS POWDER TRENDS