Kumar, Nikhil Gour, Kuldeep Singh Haider, Arsalan Kumar, Ravan Park, Sungjin 2025-01-07T02:30:38Z 2025-01-07T02:30:38Z 2024-12-30 2024-12 https://pubs.kist.re.kr/handle/201004/151475 The design and progress of smart hybrid materials are inspired by persistent challenges accompanied by the clean and green energy crisis and environmental remediation. However, the emergence of multifunctional nanomaterials has been captivating, and the real eagerness lies in decorating materials with flexible properties. The framework materials constituted with metal ions and organic ligands called metal-organic frameworks (MOFs) are recognized as promising candidates for electrocatalytic applications and gas adsorption. Still, their durability is challenged by low electrical conductivity, limited chemical stability, and intricate pores. Researchers have tried to develop MOF-assisted hybrid materials with rich surface chemistry due to their compositional versatility to improve pristine MOF stability. This review comprises the basic fundamentals and chemistry of MOFs, nitrogen reduction reaction (NRR), and electrochemical reduction of carbon dioxide (CO2RR), different types of MOF-based materials utilized for NRR and CO2RR, responsible factors, mechanistic pathways, and future viewpoints. English American Chemical Society Nanoporous Metal-Organic Frameworks for Electroreduction of Nitrogen and Carbon Dioxide: A Review Article 10.1021/acsanm.4c05030 1 ACS Applied Nano Materials, v.7, no.24, pp.28074 - 28097 ACS Applied Nano Materials 7 24 28074 28097 N scie scopus 001373333500001 2-s2.0-85211488316 Nanoscience & Nanotechnology Materials Science, Multidisciplinary Science & Technology - Other Topics Materials Science Review SINGLE-ATOM CATALYSTS DOPED CARBON ELECTROCHEMICAL SYNTHESIS N-2 REDUCTION N2 REDUCTION CO2 AMMONIA OXYGEN MOF ELECTROCATALYSTS MOFs hybrid materials NRR ammoniaproduction CO2RR