Yun, Heecheol Park, Sangwoo Choi, Jaewon Cho, Se Youn Kwak, Hyo Won 2025-03-19T15:30:12Z 2025-03-19T15:30:12Z 2025-03-19 2025-04 1381-5148 https://pubs.kist.re.kr/handle/201004/151904 Melamine sponge is widely used in various industrial applications owing to its high specific surface area and excellent mechanical properties. However, its practical use as an oil–water separation material is limited by the complex hydrophobization process and the use of non-renewable additives. Herein, we employed lignin, a wood-based biomass, as an amphiphilic connector to modify melamine foam with alkylated graphene oxide. Lignin was easily coated onto the melamine foam, enhancing its hydrophobicity and allowing for a continuous layer of alkylated graphene oxide. This process considerably improved the hydrophobicity of melamine foam, achieving a contact angle of 132.2°. Consequently, the hydrophobic melamine foam demonstrated selective oil absorption in oil-contaminated environments, with an oil adsorption capacity of 42–158 g/g and an excellent oil absorption efficiency of over 97 % even after 20 cycles. The additional alkylated graphene coating further enhanced flux when used as a filter material, enabling rapid and selective oil removal. Our study presents a straightforward, eco-friendly method for converting hydrophilic materials into hydrophobic surfaces using biomass-derived lignin. English Elsevier BV Melamine and hydrophobic graphene composite foam with lignin as a green connector for oil–water separation applications Article 10.1016/j.reactfunctpolym.2025.106173 1 Reactive and Functional Polymers, v.209 Reactive and Functional Polymers 209 N scie scopus 001410096200001 2-s2.0-85215849106 Chemistry, Applied Engineering, Chemical Polymer Science Chemistry Engineering Polymer Science Article Lignin Melamine foam Alkylated graphene oxide Oil-water separation