Akbar, Muhammad Moeez, Iqra Kim, Young Hwan Kim, Mingony Jeong, Jiwon Lee, Eunbyoul Bhatti, Ali Hussain Umar Park, Jae-Ho Chung, Kyung Yoon 2025-03-23T12:30:36Z 2025-03-23T12:30:36Z 2025-03-19 2025-05 https://pubs.kist.re.kr/handle/201004/152097 Solid electrolytes face challenges in solid-state sodium batteries (SSSBs) because of limited ionic conductivity, increased interfacial resistance, and sodium dendrite issues. In this study, we adopted a unique Sn4+ doping strategy for Na3.2Zr2Si2.2P0.8O12 (NZSP) that caused a partial structural transition from the monoclinic (C2/c) phase to the rhombohedral (R-3c) phase in Na3.2Zr1.9Sn0.1Si2.2P0.8O12 (NZSnSP1). X-ray diffraction (XRD) patterns and high-resolution transmission electron microscopy analyses were used to confirm this transition, where rhombohedral NZSnSP1 showed an increase in the Na2–O bond length compared with monoclinic NZSnSP1, increasing its triangular bottleneck areas and noticeably enhancing Na+ ionic conductivity, a higher Na transference number, and lower electronic conductivity. NZSnSP1 also showed exceptionally high compatibility with Na metal with an increased critical current density, as evidenced by symmetric cell tests. The SSSB, fabricated using Na0.9Zn0.22Fe0.3Mn0.48O2 (NZFMO), Na metal, and NZSnSP1 as the cathode, anode, and the solid electrolyte and separator, respectively, maintains 65.86% of retention in the reversible capacity over 300 cycles within a voltage range of 2.0–4.0 V at 25°C at 0.1 C. The in-situ X-ray diffraction and X-ray absorption analyses of the P and Zr K-edges confirmed that NZSnSP1 remained highly stable before and after electrochemical cycling. This crystal structure modification strategy enables the synthesis of ideal solid electrolytes for practical SSSBs. English Wiley Novel Sn-Doped NASICON-Type Na3.2Zr2Si2.2P0.8O12 Solid Electrolyte With Improved Ionic Conductivity for a Solid-State Sodium Battery Article 10.1002/cey2.717 1 Carbon Energy, v.7, no.5 Carbon Energy 7 5 Y scie scopus 001441498500001 Chemistry, Physical Energy & Fuels Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Energy & Fuels Science & Technology - Other Topics Materials Science Article PERFORMANCE MICROSTRUCTURE TEMPERATURE ORIGIN PHASE NA ionic conductivity NASICON-type solid electrolyte phase transition Sn doping solid-state battery