Kim, Min Woo Lee, Jong Min Jung, Chi-Young Cha, Jung-Eun Myung, Kwang Shik Lee, Nam Jin Kim, Nam Dong Jung, Jae Young 2025-05-11T05:30:43Z 2025-05-11T05:30:43Z 2025-05-07 2025-05 2050-7488 https://pubs.kist.re.kr/handle/201004/152402 Enhancing the durability of platinum catalysts in proton exchange membrane fuel cells (PEMFCs) remains a key challenge for long-haul truck applications. In this study, we employed a commercialized high-surface-area carbon support and performed thermal annealing under oxidizing/reducing conditions to precisely control the oxygen functional groups on its surface. Subsequently, platinum nanoparticles (Pt NPs) were uniformly dispersed on the carbon support via a polyol method. We systematically investigated the Pt NPs/carbon interface effect using advanced spectroscopic techniques combined with electrochemical surface analyses, while isolating the effects of Pt location and pore structure. Consequently, we significantly improved the durability of the platinum catalyst, with mass activity retention increasing from 40.9% to 78.6% of initial performance (0.393-0.403 A mgPt-1), and the electrochemical surface area (ECSA) rising from 57.9% to 84.2% of initial ECSA values (95-97 m2 gPt-1). These improvements were achieved while maintaining highly precise initial parameters. Through extensive material characterization, we demonstrated that the improved durability of the platinum catalyst is attributed to the increased binding energy between the oxygen functional groups and Pt nanoparticles (NPs), as well as the suppression of Pt ionization. This study highlights the crucial role of carbon supports in fuel cells and provides guidelines for optimal design, paving the way for platinum catalysts intended for long-range fuel cell applications in areas such as ecofriendly hydrogen vehicles and distributed power generation. English Royal Society of Chemistry Thermally driven oxygen functionalization for durable Pt electrocatalysts in the oxygen reduction reaction Article 10.1039/d5ta01939g 1 Journal of Materials Chemistry A, v.13, no.20, pp.14796 - 14808 Journal of Materials Chemistry A 13 20 14796 14808 N scie scopus 001466642500001 2-s2.0-105003245641 Chemistry, Physical Energy & Fuels Materials Science, Multidisciplinary Chemistry Energy & Fuels Materials Science Article CARBON NANOFIBERS CATALYSTS OXIDE PERFORMANCE DURABILITY STABILITY SUPPORT CATHODE ACID ATOM