Kim, Hyoseok Jang, Wonsik Lee, Jin Ho Lee, Hojeong Lee, Seunghyun Kim, Jongkyoung Oh, Dongrak Noh, Woo Yeong Kim, Miri Cha, Sun Gwan Kim, Jongchan Lee, Jae Sung Kwon, Youngkook Cho, Seungho 2025-11-20T23:57:00Z 2025-11-20T23:57:00Z 2025-11-11 2025-11 1433-7851 https://pubs.kist.re.kr/handle/201004/153546 Electrochemical formate (HCOO-) production via CO2 reduction reaction (CO2RR) holds great promise for carbon-neutral energy systems; however, its practical implementation is significantly hindered by the high energy demand of anodic oxygen evolution reaction (OER). Replacing OER with a more energetically and economically favorable alternative anodic reaction is therefore essential. In this study, we developed a highly efficient Cu-Ag catalyst for anodic formaldehyde oxidation reaction (FOR). Systematic investigations employing in situ Raman spectroscopy and comprehensive electrochemical analyses revealed that Cu enables an earlier onset potential for FOR, and Ag enhances formaldehyde adsorption, leading to synergistically improved performance. The optimal Cu3Ag7 catalyst exhibited superior FOR performance, with an onset potential of -0.05 V versus the reversible hydrogen electrode (V RHE) and Faradaic efficiencies for HCOO- exceeding 90% from 0.1 to 0.5 V RHE. When coupled with CO2RR, the FOR||CO2RR system enabled dual-side HCOO- production, achieving a total HCOO- yield rate of 0.39 mmol h-1 cm-2 at an ultra-low cell voltage of 0.5 V, surpassing the performance of previously reported electrochemical HCOO- production systems. Furthermore, this study presents a versatile anodic strategy that integrates FOR with a range of cathodic reactions, offering an energy-efficient chemical synthesis approach for the advancement of sustainable electrochemical technologies. English John Wiley & Sons Ltd. Energy-Efficient Dual Formate Electrosynthesis via Coupled Formaldehyde Oxidation and CO2 Reduction at Ultra-Low Cell Voltage Article 10.1002/anie.202516232 1 Angewandte Chemie International Edition, v.64, no.47 Angewandte Chemie International Edition 64 47 N scie scopus 001584936500001 2-s2.0-105018180686 Chemistry, Multidisciplinary Chemistry Article CARBON-DIOXIDE CONVERSION GLYCOL BIOCL Bimetallic catalyst CO2 reduction Formaldehyde oxidation Formate Paired electrolysis