Han, Jung Tae List, Benjamin 2026-02-19T02:00:05Z 2026-02-19T02:00:05Z 2026-02-01 2026-04 1001-604X https://pubs.kist.re.kr/handle/201004/154267 The importance of Si-stereogenic silanes has been recognized in many fields of chemical science. Consequently, numerous catalytic enantioselective methods for their synthesis have been developed. Despite these advances, such methods have traditionally relied on transition-metal catalysts, predominantly rhodium and palladium. Recently, Brønsted acid catalysts have emerged as powerful alternatives to transition-metal catalysts. In particular, imidodiphosphorimidate (IDPi) and chiral phosphoric acid (CPA) catalysts have enabled access to structurally diverse Si-stereogenic silanes, including silyl ethers, silacycles, and disiloxanes, that were not previously attainable. In this review, we describe the recent advances made in Brønsted acid catalysis for the synthesis of Si-stereogenic silanes. We also discuss the relevant background and reaction mechanisms. We hope that this review will suggest future research directions in this emerging area. English Kexue Chubaneshe/Science Press Acid-Catalyzed Synthesis of Si-Stereogenic Silanes Article 10.1002/cjoc.70447 1 Chinese Journal of Chemistry, v.44, no.8, pp.1212 - 1222 Chinese Journal of Chemistry 44 8 1212 1222 N scie scopus 001674426500001 Chemistry, Multidisciplinary Chemistry Review ASYMMETRIC-SYNTHESIS ENANTIOSELECTIVE SYNTHESIS ORGANOSILICON COMPOUNDS SILICON DESYMMETRIZATION ACCESS CONSTRUCTION CARBON SILACYCLOBUTANES HYDROSILYLATION Br & oslash nsted acids Enantioselective catalysis Organocatalysis Imidodiphosphorimidates Chiral phosphoric acids Si-stereogenic silanes Desymmetrization Dynamic kinetic asymmetric transformation