Cho, Beom-Keun Sung-Ho Huh Kim, So Hee Yu, Seungho Bae, Jong-Seong Yoo, Jung-Keun Yu, Seung-Ho 2024-01-12T06:30:57Z 2024-01-12T06:30:57Z 2023-08-22 2024-06 https://pubs.kist.re.kr/handle/201004/79682 As an alternative to Li-ion batteries, aqueous Zn batteries have gained attention due to the abundance of Zn metal, low reduction potential (？0.76？V vs. standard hydrogen electrode), and high theoretical capacity (820？mAh？g？1) of multivalent Zn2+ ion. However, the growth of Zn dendrites and the formation of irreversible surface reaction byproducts pose challenges for ensuring a long battery lifespan and commercialization. Herein, the Cu foil coated with a single-walled carbon nanotube (SWCNT) layer using a facile doctor blade casting method is utilized. The SWCNT-coated Cu foil demonstrates a significantly longer battery lifespan compared to the bare Cu in the half-cell tests. Through operando optical microscopy imaging, we are able to provide intuitive evidence that Zn deposition occurs between the carbon nanotube (CNT) coating and Cu substrate, in agreement with the computational results. Also, with various imaging techniques, the flat morphology and homogeneous distribution of Zn beneath the SWCNT layer are demonstrated. In addition, the full-cell using CNT-coated Cu exhibits a long cycle life compared to the control group, thereby demonstrating improved electrochemical performance with limited Zn for the cycling process. English Wiley Long cycle-life aqueous Zn battery enabled by facile carbon nanotube coating on Cu current collector Article 10.1002/cey2.441 1 Carbon Energy, v.6, no.6 Carbon Energy 6 6 Y scie scopus 001136409100001 Chemistry, Physical Energy & Fuels Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Energy & Fuels Science & Technology - Other Topics Materials Science Article ION ELECTRODEPOSITION ELECTROLYTE FUTURE aqueous Zn battery carbon nanotube operando imaging surface coating