Kim, Han Byeol Jeong, Hee Jin Cheong Jaeeun Lee, Jae Kyun Lee, Duck-Hyung Han, Seojung 2024-01-12T06:35:21Z 2024-01-12T06:35:21Z 2023-05-30 2023-07 0022-3263 https://pubs.kist.re.kr/handle/201004/79890 A mild,efficient, and transition-metal-free three-component couplingreaction involving arynes, phosphites, and aldehydes was establishedto afford 3-mono-substituted benzoxaphosphole 1-oxides. A range of3-mono-substituted benzoxaphosphole 1-oxides was obtained from botharyl- and aliphatic-substituted aldehydes in moderate to good yields.Moreover, the synthetic utility of the reaction was demonstrated bya Gram-scale reaction and the transformation of the products intovarious P-containing bicycles. English American Chemical Society Three-Component Coupling Reactions Involving Arynes, Phosphites, and Aldehydes toward 3-Mono-Substituted Benzoxaphosphole 1-Oxides Article 10.1021/acs.joc.3c00438 1 The Journal of Organic Chemistry, v.88, no.13, pp.8465 - 8479 The Journal of Organic Chemistry 88 13 8465 8479 N scie scopus 001011705300001 Chemistry, Organic Chemistry Article