Copper oxide-graphene oxide nanocomposite: efficient catalyst for hydrogenation of nitroaromatics in water

Authors
Zhang, KaiqiangSuh, Jun MinLee, Tae HyungCha, Joo HwanChoi, Ji-WonJang, Ho WonVarma, Rajender S.Shokouhimehr, Mohammadreza
Issue Date
2019-02
Publisher
Springer | Korea Nano Technology Research Society
Citation
Nano Convergence, v.6
Abstract
A low-cost nanocomposite catalyst containing copper oxide (CuO) nanoparticles (NPs) on graphene oxide (GO) was fabricated by a facile hydrothermal self-assembly process.The segregated CuO NPs and GO exhibited negligible catalytic activities for the reduction of nitroaromatics. However, their hybrid composite accomplished facile reduction with high conversions for several substituted nitroaromatics in aqueous NaBH4 solution; synergetic coupling effect of CuO NPs with GO in the nanocomposite catalyst provided excellent catalytic activity. The nanocomposite catalyst could be separated from the reaction mixture and recycled consecutively.
Keywords
CORE-SHELL NANOCATALYSTS; PALLADIUM NANOPARTICLES; HETEROGENEOUS REDUCTION; SELECTIVE HYDROGENATION; MESOPOROUS SILICA; HIGHLY EFFICIENT; 4-NITROPHENOL; NANOSPHERES; SURFACE; Synergistic effect; Copper oxide; Graphene oxide; Hydrothermal; Hydrogenation
ISSN
2196-5404
URI
https://pubs.kist.re.kr/handle/201004/120434
DOI
10.1186/s40580-019-0176-3
Appears in Collections:
KIST Article > 2019
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