SBA-15-supported copper (II) complex: An efficient heterogeneous catalyst for azide-alkyne cycloaddition in water

Abstract

The reaction of the functionalized mesoporous SBA-15 in absolute ethanol with copper (II) acetate afforded a novel Cu-II-Schiff base/SBA-15 catalyst. The compound Cu-II-Schiff base/SBA-15 was characterized by IR spectroscopy, small-angle X-ray diffraction (SAX), Energy Dispersive X-ray Spectroscopy (EDXS), X-ray Absorption Near Edge Structure (XANES), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), and N-2 adsorption/desorption studies. Further, the catalytic activity of this well-defined material was tested in three-component Copper-catalyzed Azide-Alkyne Cycloaddition (CuAAC) reactions to obtain 1,4-disubstituted-1,2,3-triazoles in good to excellent yields from an organic halide, sodium azide, and alkyne in water as a green solvent. More importantly, the catalyst can be recovered and reused efficiently up to five consecutive cycles with negligible loss of catalytic activity. (C) 2018 Sharif University of Technology. All rights reserved.