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POSS-Based Covalent Networks: Supporting and Stabilizing Pd for Heck Reaction in Aqueous Media

Authors
Arsalani, Nasser; Akbari, Ali; Amini, Mojtaba; Jabbari, Esmaiel; Gautam, Sanjeev; Chae, Keun Hwa
Issue Date
2017-04
Publisher
SPRINGER
Citation
CATALYSIS LETTERS, v.147, no.4, pp.1086 - 1094
Abstract
Palladium nanoparticles supported on Incompletely Condensed Polyhedral Oligomeric Silsesquioxane (IC-POSS) based poly (Acrylamide-co-Hydroxy ethyl methacrylate) as a novel nanohybrid catalyst were synthesized and characterized. This catalyst was found to be an efficient and reusable heterogeneous catalyst for the Heck reaction using water as the solvent in the absence of a phosphine ligand and phase transfer catalyst.
Keywords
POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; CATALYTIC-ACTIVITY; HYBRID NANOCOMPOSITES; MIZOROKI-HECK; SCHIFF-BASE; NANOPARTICLES; WATER; SONOGASHIRA; EPOXIDATION; COUPLINGS; POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; CATALYTIC-ACTIVITY; HYBRID NANOCOMPOSITES; MIZOROKI-HECK; SCHIFF-BASE; NANOPARTICLES; WATER; SONOGASHIRA; EPOXIDATION; COUPLINGS; Polyhedral Oligomeric Silsesquioxane; Hybrid copolymer; Heck reaction; And radical polymerization
ISSN
1011-372X
URI
https://pubs.kist.re.kr/handle/201004/122925
DOI
10.1007/s10562-016-1954-8
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KIST Article > 2017
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