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Mizoroki-Heck reaction over palladium nanoparticles supported on WO3

Authors
Amini, Mojtaba; Heydarloo, Dina Bahrami; Rahimi, Mohammad; Kim, Min Gyu; Gautam, Sanjeev; Chae, Keun Hwa
Issue Date
2016-11
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
MATERIALS RESEARCH BULLETIN, v.83, pp.179 - 185
Abstract
Palladium nanoparticles supported on metal oxide WO3 were synthesized and the physicochemical properties of compounds were characterized by X-ray diffraction (XRD), X-ray absorption near edge spectroscopy (XANES) at O and Pd IC-edges, energy dispersive X-ray analysis (EDX), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The catalytic activity of compounds in the carbon-carbon coupling reactions of aryl halides with olefins (Mizoroki-Heck reaction) was studied. The catalyst can be easily separated from the reaction mixture and reused after washing without reduction in activity. (C) 2016 Elsevier Ltd. All rights reserved.
Keywords
CROSS-COUPLING REACTIONS; PD NANOPARTICLES; HETEROGENEOUS CATALYSIS; ELECTRONIC-STRUCTURE; ORGANIC-CHEMISTRY; ACTIVE CATALYST; COMPLEXES; ARYLATION; EFFICIENT; LIGAND; CROSS-COUPLING REACTIONS; PD NANOPARTICLES; HETEROGENEOUS CATALYSIS; ELECTRONIC-STRUCTURE; ORGANIC-CHEMISTRY; ACTIVE CATALYST; COMPLEXES; ARYLATION; EFFICIENT; LIGAND; Nanostructures; Chemical synthesis; X-ray diffraction; Transmission electron microscopy (TEM); Catalytic properties
ISSN
0025-5408
URI
https://pubs.kist.re.kr/handle/201004/123521
DOI
10.1016/j.materresbull.2016.06.007
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KIST Article > 2016
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