Supported metal nanoparticles: Their catalytic applications to selective alcohol oxidation

Authors
Hussain, M.A.Joseph, N.Kang, O.Cho, Y.-H.Um, B.-H.Kim, J.W.
Issue Date
2016-06
Publisher
Korean Society of Industrial Engineering Chemistry
Citation
Applied Chemistry for Engineering, v.27, no.3, pp.227 - 238
Abstract
This review article highlights different types of nano-sized catalysts for the selective alcohol oxidation to form aldehydes (or ketones) with supported or immobilized metal nanoparticles. Metal nanoparticle catalysts are obtained through dispersing metal nanoparticles over a solid support with a large surface area. The nanocatalysts have wide technological applications to industrial and academic fields such as organic synthesis, fuel cells, biodiesel production, oil cracking, energy conversion and storage, medicine, water treatment, solid rocket propellants, chemicals and dyes. One of main reactions for the nanocatalyst is an aerobic oxidation of alcohols to produce important intermediates for various applications. The oxidation of alcohols by supported nanocatalysts including gold, palladium, ruthenium, and vanadium is very economical, green and environmentally benign reaction leading to decrease byproducts and reduce the cost of reagents as opposed to stoichiometric reactions. In addition, the room temperature alcohol oxidation using nanocatalysts is introduced. ? 2016 The Korean Society of Industrial and Engineering Chemistry. All rights reserved.
Keywords
Alcohol oxidation; Aldehyde; Metal nanoparticle; Nanocatalyst; Supported metal
ISSN
1225-0112
URI
https://pubs.kist.re.kr/handle/201004/124041
DOI
10.14478/ace.2016.1047
Appears in Collections:
KIST Article > 2016
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