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Elucidating the intercalation mechanism of zinc ions into alpha-MnO2 for rechargeable zinc batteries

Authors: Lee, Boeun; Lee, Hae Ri; Kim, Haesik; Chung, Kyung Yoon; Cho, Byung Won; Oh, Si Hyoung

Issue Date: 2015-06

Publisher: ROYAL SOC CHEMISTRY

Citation: CHEMICAL COMMUNICATIONS, v.51, no.45, pp.9265 - 9268

Abstract: The intercalation mechanism of zinc ions into 2 x 2 tunnels of an alpha-MnO2 cathode for rechargeable zinc batteries was revealed. It involves a series of single and two-phase reaction steps and produces buserite, a layered compound with an interlayer spacing of 11 angstrom as a discharge product.

Keywords: CRYSTAL-STRUCTURE; MANGANESE OXIDES; TODOROKITE; CATHODE; BIRNESSITE; CHALCOPHANITE; BUSERITE; MNO2; CRYSTAL-STRUCTURE; MANGANESE OXIDES; TODOROKITE; CATHODE; BIRNESSITE; CHALCOPHANITE; BUSERITE; MNO2; rechargeable zinc battery; alpha manganese dioxide; in situ X-ray diffraction; intercalation mechanism

ISSN: 1359-7345

URI: https://pubs.kist.re.kr/handle/201004/125411

DOI: 10.1039/c5cc02585k

Appears in Collections:: KIST Article > 2015

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