(E)-2,2′-[3-(4-Chlorophenyl)prop-2-ene-1,1-diyl]bis(3-hydroxy-5, 5-dimethylcyclohex-2-en-1-one)

Authors
Cha, J.H.Lee, J.K.Min, S.-J.Cho, Y.S.Park, J.
Issue Date
2013-08
Citation
Acta Crystallographica Section E: Structure Reports Online, v.69, no.8
Abstract
The title compound, C25H29ClO4, adopts a trans conformation about the C=C double bond and the dimethylcyclohexenone rings both show an envelope conformation with the dimethyl-substituted C atom as the flap. In the molecule, the hydroxy and carbonyl groups form two intramolecular O - H?O hydrogen bonds typical for xanthene derivatives. In the crystal, weak C - H?O hydrogen bonds link the molecules into chains running parallel to the a-axis direction.
Keywords
data-to-parameter ratio = 18.4; meanω(C - C) = 0.003 A °; Rfactor = 0.045; single-crystal X-ray study; T = 296 K; wRfactor = 0.135
ISSN
1600-5368
URI
https://pubs.kist.re.kr/handle/201004/127848
DOI
10.1107/S1600536813020357
Appears in Collections:
KIST Article > 2013
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