Effect of the cation part of imidazolium ionic liquids on synthesis of palladium particle

Abstract

Palladium particles were synthesized by conventional chemical reduction method with ionic liquids. The size and shape of palladium particles were significantly affected by the cation parts of ionic liquids. This is mainly attributed to the different stabilities of the ionic liquid structure formed by the physical bond between the cation parts. Among ionic liquids with [BF4] as an anion part, the hexyl substituent in the cation parts was more effective to synthesize palladium particles with the smaller size and more uniform shape. ？ 2012 The Korean Society of Industrial and Engineering Chemistry. All rights reserved.