(E)-2,2 '-[3-(2-Nitrophenyl)prop-2-ene-1,1-diyl]bis(3-hydroxy-5,5-dimethylcycloh ex-2-en-1-one)

Authors
Cha, Joo HwanKim, Young HeeMin, Sun-JoonCho, Yong SeoLee, Jae Kyun
Issue Date
2011-12
Publisher
WILEY-BLACKWELL
Citation
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, v.67, pp.O3153 - U908
Abstract
In the title compound, C25H29NO6, each of the cyclohexenone rings adopts a half-chair conformation. Each of the pairs of hydroxy and carbonyl O atoms are oriented to allow for the formation of intramolecular O-H center dot center dot center dot O hydrogen bonds, which are typical of xanthene derivatives. The nitro group is rotationally disordered over two orientations in a 0.544 (6):0.456 (6) ratio. In the crystal, weak intermolecualr C-H center dot center dot center dot O hydrogen bonds link molecules into layers parallel to the ab plane.
Keywords
data-to-parameter ratio = 13.4; disorder in main residue; mean σ(C-C) = 0.007 ?; R factor = 0.064; single-crystal X-ray study; T = 298 K; wR factor = 0.191
ISSN
1600-5368
URI
https://pubs.kist.re.kr/handle/201004/129758
DOI
10.1107/S1600536811043686
Appears in Collections:
KIST Article > 2011
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