(E)-2,2 '-[3-(2-Nitrophenyl)prop-2-ene-1,1-diyl]bis(3-hydroxy-5,5-dimethylcycloh ex-2-en-1-one)
- Authors
- Cha, Joo Hwan; Kim, Young Hee; Min, Sun-Joon; Cho, Yong Seo; Lee, Jae Kyun
- Issue Date
- 2011-12
- Publisher
- WILEY-BLACKWELL
- Citation
- ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, v.67, pp.O3153 - U908
- Abstract
- In the title compound, C25H29NO6, each of the cyclohexenone rings adopts a half-chair conformation. Each of the pairs of hydroxy and carbonyl O atoms are oriented to allow for the formation of intramolecular O-H center dot center dot center dot O hydrogen bonds, which are typical of xanthene derivatives. The nitro group is rotationally disordered over two orientations in a 0.544 (6):0.456 (6) ratio. In the crystal, weak intermolecualr C-H center dot center dot center dot O hydrogen bonds link molecules into layers parallel to the ab plane.
- Keywords
- data-to-parameter ratio = 13.4; disorder in main residue; mean σ(C-C) = 0.007 ?; R factor = 0.064; single-crystal X-ray study; T = 298 K; wR factor = 0.191
- ISSN
- 1600-5368
- URI
- https://pubs.kist.re.kr/handle/201004/129758
- DOI
- 10.1107/S1600536811043686
- Appears in Collections:
- KIST Article > 2011
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