DSpace at KISTKIST Article2005

Stereoselective syntheses of rolliniastatin 1, rollimembrin, and membranacin

Authors
Keum, G; Hwang, CH; Kang, SB; Kim, Y; Lee, E
Issue Date
2005-07-27
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.127, no.29, pp.10396 - 10399
Abstract
A radical cyclization of beta-alkoxyvinyl sulfoxides-Pummerer rearrangement-allylation protocol was successfully applied to the synthesis of the threo/cis/threo/cis/erythro bis-oxolane moiety in rolliniastatin 1 (1), rollimembrin (2), and membranacin (3).
Keywords
MITOCHONDRIAL COMPLEX-I; ANNONACEOUS ACETOGENINS; RADICAL CYCLIZATION; RECENT PROGRESS; CIS-SOLAMIN; SULFOXIDES; MITOCHONDRIAL COMPLEX-I; ANNONACEOUS ACETOGENINS; RADICAL CYCLIZATION; RECENT PROGRESS; CIS-SOLAMIN; SULFOXIDES; radical cyclization; complex 1 inhibitor; rolliniastatin; rollimembrin; membranacin; acetogenin; tetrahydrofuran; cross metathesis; beta-alkoxyvinyl sulfoxide
ISSN
0002-7863
URI
https://pubs.kist.re.kr/handle/201004/136279
DOI
10.1021/ja0526867
Appears in Collections:
KIST Article > 2005
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