DSpace at KIST: Monolayer protected Au cluster (MPC)-bound Ru-carbene complex: synthesis and its catalytic activity in ring-closing olefin metathesis

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Monolayer protected Au cluster (MPC)-bound Ru-carbene complex: synthesis and its catalytic activity in ring-closing olefin metathesis

Authors: Lee, BS; Namgoong, SK; Lee, SG

Issue Date: 2005-06-27

Publisher: PERGAMON-ELSEVIER SCIENCE LTD

Citation: TETRAHEDRON LETTERS, v.46, no.26, pp.4501 - 4503

Abstract: Monolayer-protected gold cluster (Au-MPC)-bound Ru-carbene complex (MPC-7) has been synthesized and examined its catalytic activity in ring-closing olefin metathesis. The MPC-7 showed almost the same catalytic activity with that of simple molecules (Grubbs Ru-complex 1b and the thioacetate-functionalized Ru-complex 8) and reused several times. (c) 2005 Elsevier Ltd. All rights reserved.

Keywords: SELF-ASSEMBLED MONOLAYERS; RECYCLABLE CATALYST; GOLD; RUCL2(=CHR)(PR(3))(2); IMMOBILIZATION; EFFICIENT; SELF-ASSEMBLED MONOLAYERS; RECYCLABLE CATALYST; GOLD; RUCL2(=CHR)(PR(3))(2); IMMOBILIZATION; EFFICIENT; monolayer; gold cluster; Ru-carbene complex; metathesis

ISSN: 0040-4039

URI: https://pubs.kist.re.kr/handle/201004/136348

DOI: 10.1016/j.tetlet.2005.04.123

Appears in Collections:: KIST Article > 2005

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