DSpace at KIST: Indium(III) halide mediated S(N)2 ' reactions of substituted allenols: Synthesis of 2-halo-1,3-dienes

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Indium(III) halide mediated S(N)2 ' reactions of substituted allenols: Synthesis of 2-halo-1,3-dienes

Authors: Cho, YS; Jun, BK; Pae, AN; Cha, JH; Koh, HY; Chang, MH; Han, SY

Issue Date: 2004-11-03

Publisher: GEORG THIEME VERLAG KG

Citation: SYNTHESIS-STUTTGART, no.16, pp.2620 - 2624

Abstract: Treatment of various substituted allenols with indium(III) halide in benzene gave (Z)- or (E)-2-halo-1,3-dienes in moderate to good yields. In most cases, (2Z)-halo-1,3-dienes were obtained as major products.

Keywords: AQUEOUS-MEDIA; DERIVATIVES; (Z,E)-2-BROMO-1,3-DIENES; ALLENYLATION; ALLYLATION; ALDEHYDES; ACETATES; ETHERS; WATER; TIN; AQUEOUS-MEDIA; DERIVATIVES; (Z,E)-2-BROMO-1,3-DIENES; ALLENYLATION; ALLYLATION; ALDEHYDES; ACETATES; ETHERS; WATER; TIN; allenol; indium(III) halide; 2-halo-1,3-diene; S(N)2 ' reaction

ISSN: 0039-7881

URI: https://pubs.kist.re.kr/handle/201004/137067

DOI: 10.1055/s-2004-831209

Appears in Collections:: KIST Article > 2004

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