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dc.contributor.authorDonghee Gueon-
dc.contributor.authorJaehyun Lee-
dc.contributor.authorJun Hyuk Moon-
dc.identifier.citationVOL 6, NO 44, 38012-38017-
dc.description.abstractThe uniform dispersion of Si materials in a carbon matrix while maintaining the nanomorphology of Si is required to achieve higher performance lithium-ion batteries (LIBs). Carbon-coated silicon nanoparticles embedded in monodisperse carbon spheres (C-SNP/CSs) were assembled by a simple mixing approach. We obtained high silicon contents up to 56 wt% for the composite electrodes. The C-SNP/CS anodes delivered a reversible specific capacity of 1230 mA h g&#8722-
dc.description.abstract1 for 56 wt% Si and 953 mA h g&#8722-
dc.description.abstract1 for 44 wt% Si at 800 mA g&#8722-
dc.description.abstract1 after 150 charge/discharge cycles. The capacity retention after 150 cycles was 73% for the 56 wt% Si and 86% for 44 wt% Si C-SNP/CS electrodes, while the bare C-SNPs without CSs displayed only 32% retention. The high cycle performance indicates that the CSs effectively alleviated the mechanical stress induced by the large volume changes of Si during the charge/discharge cycles. Moreover, the high capacity retention reveals the high electrical conductivity of the electrodes, provided by the assembled morphology the CSs and the carbon-shell on the silicon nanoparticles(SNPs). The use of CSs with C-SNPs is a facile method to obtain a uniformly-dispersed mixture and can be readily scaled for practical applications.-
dc.publisherRSC advances-
dc.subjectCarbon coated silicon nanoparticle-
dc.subjectlithium ion batteries-
dc.subjectcarbon sphere-
dc.titleCarbon-coated silicon nanoparticle-embedded carbon sphere assembly electrodes with enhanced performance for lithium-ion batteries-
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