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dc.contributor.author황승상-
dc.contributor.author백경열-
dc.contributor.author조영열-
dc.contributor.author알버트 이성수-
dc.contributor.author최승석-
dc.date.accessioned2021-06-09T04:18:31Z-
dc.date.available2021-06-09T04:18:31Z-
dc.date.issued2017-08-
dc.identifier.citationVOL 17, NO 8-5565-
dc.identifier.issn1533-4880-
dc.identifier.other49347-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/66237-
dc.description.abstractThrough UV-initiated thiol-ene click chemistry, carbazole-substituted ladder-like structured polysilsesquioxane and cage-structured polyhedral oligomeric silsesquioxane (T8-POSS) compounds were synthesized and fully characterized. Perfectly carbazole-substituted T8-POSS was synthesized via post-modifications of a mercaptopropyl T8-POSS, while the ladder polysilsesquioxane was synthesized through a base-catalyzed hydrolysis-polycondensation reaction with a carbazole-substituted trialkoxysilane monomer. Through a comparative evaluation of the thermal, mechanical, and photophysical properties of the synthesized compounds, we demonstrate the utility and superiority of the ladder-like structure over the T8-POSS material.-
dc.publisherJournal of nanoscience and nanotechnology-
dc.subjectPolysilsesquioxane-
dc.subjectThiol-ene click reaction-
dc.subjectFluorescent-
dc.titleThermal, Mechanical, and Photophysical Properties of Carbazole-Substituted POSS and Ladder Polysilsesquioxane-
dc.typeArticle-
dc.relation.page55625565-
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