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dc.contributor.author강택-
dc.contributor.author윤여권-
dc.contributor.author이희윤-
dc.date.accessioned2021-06-09T04:19:32Z-
dc.date.available2021-06-09T04:19:32Z-
dc.date.issued2011-02-
dc.identifier.citationVOL 6, NO 2-651-
dc.identifier.issn1861-4728-
dc.identifier.other50268-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/67144-
dc.description.abstractA thorough study on the diastereoselectivity in the TMM diyl mediated [2+3] cycloaddition reaction of monosubstituted linear substrates to form angularly fused triquinanes was carried out. Substitution at position 3 provided complete diastereoselectivity, while positions 1 and 4 induced marginal stereoselectivity. Position 2 did not show any influence on the diastereoselectivity. Position 4 turned out to be incompatible with the cycloaddition reaction as the carbene intermediate underwent O-Si bond insertion to form a dihydrofuran ring.-
dc.publisherChemistry, an Asian journal-
dc.subjectcarbenes-
dc.subjectcycloaddition-
dc.subjectstereoselectivity-
dc.subjecttrimethylenemethane-
dc.subjecttriquinane-
dc.titleStereoselectivity in Trimethylenemethane (TMM) Diyl Mediated Cycloaddition Reaction to Angularly Fused Triquinanes-
dc.typeArticle-
dc.relation.page646651-
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