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dc.contributor.author한서정-
dc.contributor.authorMin-ho Hwang-
dc.contributor.authorDuck-Hyung Lee-
dc.date.accessioned2021-06-09T04:19:49Z-
dc.date.available2021-06-09T04:19:49Z-
dc.date.issued2013-07-
dc.identifier.citationVOL 15, NO 13-3321-
dc.identifier.issn1523-7060-
dc.identifier.other50496-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/67366-
dc.description.abstractA convergent and enantioselective total synthesis of (-)-amphidinolide O (1) and P (2), 15-membered macrolides with seven chiral centers along with many functional groups, is described. The key reactions include enantioselective Brown allylation, anti- and syrr-selective aldol reactions, (E)-selective olefin metathesis, conformation-controlled stereoselective epoxidation, and selective introduction of the exomethylene group. Assignments of the absolute stereochemistries of the natural (+)-amphidinolide O (ent-1) and P (ent-2) are also discussed in detail.-
dc.publisherOrganic letters-
dc.titleConvergent and Enantioselective Total Synthesis of (-)-Amphidinolide O and (-)-Amphidinolide P-
dc.typeArticle-
dc.relation.page33183321-
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