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Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3- bromooxindoles with a-arylated malonate esters

Title: Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3- bromooxindoles with a-arylated malonate esters

Authors: 한서정; Chung Whan Lee; Scott C. Virgil; Brian M. Stoltz

Issue Date: 2015-06

Publisher: Tetrahedron

Citation: VOL 71, NO 22-3670

Abstract: An improved method for the asymmetric alkylation of 3-bromooxindoles with alpha-arylated malonate esters is described. The asymmetric alkylation demonstrated was achieved up to 70% ee utilizing a copper(II) bis(phosphine) complex.

URI: https://pubs.kist.re.kr/handle/201004/67369

ISSN: 0040-4020

Appears in Collections:: KIST Publication > Article

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