Grain Boundary Softening: A Potential Mechanism for Lithium Metal Penetration through Stiff Solid Electrolytes
- Grain Boundary Softening: A Potential Mechanism for Lithium Metal Penetration through Stiff Solid Electrolytes
- 류승호; Donald J. Siegel
- Issue Date
- ACS Applied Materials & Interfaces
- VOL 10, NO 44-38158
- Models based on linear elasticity suggest that a solid electrolyte with a high shear modulus will suppress “dendrite” formation in batteries that use metallic lithium as the negative electrode. Nevertheless, recent experiments find that lithium can penetrate stiff solid electrolytes through microstructural features, such as grain boundaries. This failure mode emerges even in cases where the electrolyte has an average shear modulus that is an order of magnitude larger than that of Li. Adopting the solid-electrolyte Li7La3Zr2O12 (LLZO) as a prototype, here we demonstrate that significant softening in elastic properties occurs in nanoscale regions near grain boundaries. Molecular dynamics simulations performed on tilt and twist boundaries reveal that the grain boundary shear modulus is up to 50% smaller than in bulk regions. We propose that inhomogeneities in elastic properties arising from microstructural features provide a mechanism by which soft lithium can penetrate ostensibly stiff solid electrolytes.
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