Realization of Excitation Wavelength Independent Blue Emission of ZnO Quantum Dots with Intrinsic Defects

Abstract

Ecofriendly cation metal oxide quantum dots (QDs) are one of the promising candidates to replace for QDs containing expensive indium (In) or hazardous Cd- and Pb-elements. Super-E-g excitation wavelength (lambda(ex)) dependent Zn-i-V-O complex defects related characteristic emissions of green, yellow, and orange-red from ZnO QDs are completely inhibited by reducing oxygen vacancies through the hybridization of Zn interstitials in ZnO QDs with antibonding O-states of graphene oxide (GO) QDs. Thus, only lambda(ex) independent violet-purple-blue (V-P-B) emission resulting from transitions among Frenkel pairs (Zn-i(0)-V-Zn) and the defects Zn-i(0)-O-i in ZnO-GO QDs with a high photoluminescence quantum yield (PLQY) of 92% is successfully achieved. White-light emission from PL QD-LEDs is achieved using a mixture of ZnO and ZnO-GO QDs with CIE (0.32, 0.34) excited by a UV LEDs chip (lambda = 365 nm). Further, ZnO-GO QD-based deep-blue LEDs (lambda = 438 nm) with luminance of 1980 cd/m(2), a luminous efficacy (LE) of 2.53 cd/ A, and external quantum efficiency (EQE) of 2.78% with CIE (0.16, 0.11) are also realized.