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dc.contributor.authorChoi, Insoo-
dc.contributor.authorJung, Yoo Eil-
dc.contributor.authorYoo, Sung Jong-
dc.contributor.authorKim, Jin Young-
dc.contributor.authorKim, Hyoung-Juhn-
dc.contributor.authorLee, Chang Yeon-
dc.contributor.authorJang, Jong Hyun-
dc.date.accessioned2024-01-20T02:02:51Z-
dc.date.available2024-01-20T02:02:51Z-
dc.date.created2021-09-01-
dc.date.issued2017-03-
dc.identifier.issn2093-8551-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/123022-
dc.description.abstractElectrochemical conversion of CO2 and production of H-2 were attempted on a three-dimensionally ordered, porous metal organic framework (MOF-74) in which transition metals (Co, Ni, and Zn) were impregnated. A lab-scale proton exchange membrane-based electrolyzer was fabricated and used for the reduction of CO2. Real-time gas chromatography enabled the instantaneous measurement of the amount of carbon monoxide and hydrogen produced. Comprehensive calculations, based on electrochemical measurements and gaseous product analysis, presented a time-dependent selectivity of the produced gases. M-MOF-74 samples with different central metals were successfully obtained because of the simple synthetic process. It was revealed that Co- and Ni-MOF-74 selectively produce hydrogen gas, while Zn-MOF-74 successfully generates a mixture of carbon monoxide and hydrogen. The results indicated that M-MOF-74 can be used as an electrocatalyst to selectively convert CO2 into useful chemicals.-
dc.languageEnglish-
dc.publisherKOREAN ELECTROCHEMISTRY SOC-
dc.subjectMETAL-ORGANIC FRAMEWORKS-
dc.subjectHYDROGEN EVOLUTION REACTION-
dc.subjectCARBON-DIOXIDE-
dc.subjectSELECTIVE CONVERSION-
dc.subjectAU NANOPARTICLES-
dc.subjectREDUCTION-
dc.subjectCATALYSTS-
dc.subjectFORMATE-
dc.subjectMETHANOL-
dc.subjectOXIDE-
dc.titleFacile Synthesis of M-MOF-74 (M=Co, Ni, Zn) and its Application as an ElectroCatalyst for Electrochemical CO2 Conversion and H-2 Production-
dc.typeArticle-
dc.identifier.doi10.5229/JECST.2017.8.1.61-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF ELECTROCHEMICAL SCIENCE AND TECHNOLOGY, v.8, no.1, pp.61 - 68-
dc.citation.titleJOURNAL OF ELECTROCHEMICAL SCIENCE AND TECHNOLOGY-
dc.citation.volume8-
dc.citation.number1-
dc.citation.startPage61-
dc.citation.endPage68-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000404287100008-
dc.identifier.scopusid2-s2.0-85020459113-
dc.relation.journalWebOfScienceCategoryElectrochemistry-
dc.relation.journalResearchAreaElectrochemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusMETAL-ORGANIC FRAMEWORKS-
dc.subject.keywordPlusHYDROGEN EVOLUTION REACTION-
dc.subject.keywordPlusCARBON-DIOXIDE-
dc.subject.keywordPlusSELECTIVE CONVERSION-
dc.subject.keywordPlusAU NANOPARTICLES-
dc.subject.keywordPlusREDUCTION-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusFORMATE-
dc.subject.keywordPlusMETHANOL-
dc.subject.keywordPlusOXIDE-
dc.subject.keywordAuthorElectrochemical conversion-
dc.subject.keywordAuthorCO2-
dc.subject.keywordAuthorH-2-
dc.subject.keywordAuthorMetal organic framework-
dc.subject.keywordAuthorCatalyst-
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