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dc.contributor.authorHan, Joon Soo-
dc.contributor.authorKang, Seung-Hyun-
dc.contributor.authorJung, Ii Nam-
dc.contributor.authorYoo, Bok Ryul-
dc.date.accessioned2024-01-20T03:03:24Z-
dc.date.available2024-01-20T03:03:24Z-
dc.date.created2021-09-05-
dc.date.issued2016-10-25-
dc.identifier.issn1226-086X-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/123544-
dc.description.abstractAromatic carbonyl compounds such as aromatic aldehydes and ketones [(RRC)-R-1-C-2=O: R-1=H; R-2=Ph (1a), 2,4-Cl2Ph (1b), 2,4-Me2Ph (1c): R-1=Ph; R-2=Ph (1d), 4-C1Ph (1e), 4-MePh (2f), 2,4-Me2Ph (1g) undergo the deoxygenative silylation with HSiCl3 in the presence of Bu4PCl at 150 degrees C within 1.0-1.5 h to give arylmethyltrichlorosilanes 2 ((RRCH)-R-1-C-2-SiCl3) in high yields (85-95%). The reactivity of aromatic carbonyl compounds decreases with increasing the electron withdrawing ability of substituent(s) on the benzene ring. A highly efficient synthetic route to arylmethyltrichlorosilanes has been developed starting from aromatic aldehydes and ketones in this study. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE INC-
dc.subjectC COUPLING REACTION-
dc.subjectORGANOSILICON COMPOUNDS-
dc.subjectPENTACOORDINATE HYDRIDOSILICATES-
dc.subjectSELECTIVE REDUCTION-
dc.subjectTRICHLOROSILANE-
dc.subjectHYDROSILANES-
dc.subjectREACTIVITY-
dc.subjectKETONES-
dc.subjectHYDROSILYLATION-
dc.subjectDIHYDRIDOSILICATES-
dc.titleDeoxygenative silylation of aromatic carbonyl compounds with HSiCl3 in the presence of quaternary phosphonium chloride: A facile route to arylmethyltrichlorosilane-
dc.typeArticle-
dc.identifier.doi10.1016/j.jiec.2016.08.015-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.42, pp.157 - 161-
dc.citation.titleJOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY-
dc.citation.volume42-
dc.citation.startPage157-
dc.citation.endPage161-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.description.journalRegisteredClasskci-
dc.identifier.kciidART002157135-
dc.identifier.wosid000384873100022-
dc.identifier.scopusid2-s2.0-84991030225-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryEngineering, Chemical-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaEngineering-
dc.type.docTypeArticle-
dc.subject.keywordPlusC COUPLING REACTION-
dc.subject.keywordPlusORGANOSILICON COMPOUNDS-
dc.subject.keywordPlusPENTACOORDINATE HYDRIDOSILICATES-
dc.subject.keywordPlusSELECTIVE REDUCTION-
dc.subject.keywordPlusTRICHLOROSILANE-
dc.subject.keywordPlusHYDROSILANES-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordPlusKETONES-
dc.subject.keywordPlusHYDROSILYLATION-
dc.subject.keywordPlusDIHYDRIDOSILICATES-
dc.subject.keywordAuthorTrichlorosilane-
dc.subject.keywordAuthorAromatic carbonyl compounds-
dc.subject.keywordAuthorArylmethyltrichlorosilane-
dc.subject.keywordAuthorSi-C coupling-
dc.subject.keywordAuthorDeoxygenative silylation-
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