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dc.contributor.authorYati, Indri-
dc.contributor.authorDwiatmoko, Adid Adep-
dc.contributor.authorYoon, Ji Sun-
dc.contributor.authorChoi, Jae-Wook-
dc.contributor.authorSuh, Dong Jin-
dc.contributor.authorJae, Jungho-
dc.contributor.authorHa, Jeong-Myeong-
dc.date.accessioned2024-01-20T03:33:15Z-
dc.date.available2024-01-20T03:33:15Z-
dc.date.created2021-09-05-
dc.date.issued2016-08-25-
dc.identifier.issn0926-860X-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/123774-
dc.description.abstractAl2O3-cogelled Ru nanoparticle (Ru@Al) catalyst was prepared by a one-pot in-situ alumina gelation method using a PVP-stabilized Ru colloid solution. The Ru@Al catalyst exhibited excellent catalytic activity during the liquid-phase hydrodeoxygenation of vanillin, demonstrating 100% conversion, as well as significantly higher yields of fully deoxygenated compounds compared to other conventional alumina supported Ru catalysts. We also observed better selectivity to deoxygenated dimers with the Ru@Al catalyst. The improved catalytic selectivity was attributed to the hypothesized three-dimensional structures of Al2O3 surrounding the Ru nanoparticles, which improved the two-step reaction, containing the dimerization of the phenolic compounds and the hydrodeoxygenation of phenolic dimers to produce deoxygenated high-carbon-number hydrocarbons. (C) 2016 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE BV-
dc.subjectSELECTIVE HYDRODEOXYGENATION-
dc.subjectWATER/OIL INTERFACE-
dc.subjectBIOFUEL UPGRADE-
dc.subjectMETAL-CATALYSTS-
dc.subjectMODEL COMPOUNDS-
dc.subjectPYROLYSIS OIL-
dc.subjectAQUEOUS-PHASE-
dc.subjectHYDROGENOLYSIS-
dc.subjectBIOMASS-
dc.subjectFUELS-
dc.titleOne-pot catalytic reaction to produce high-carbon-number dimeric deoxygenated hydrocarbons from lignin-derived monophenyl vanillin using Al2O3-cogelled Ru nanoparticles-
dc.typeArticle-
dc.identifier.doi10.1016/j.apcata.2016.07.012-
dc.description.journalClass1-
dc.identifier.bibliographicCitationAPPLIED CATALYSIS A-GENERAL, v.524, pp.243 - 250-
dc.citation.titleAPPLIED CATALYSIS A-GENERAL-
dc.citation.volume524-
dc.citation.startPage243-
dc.citation.endPage250-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000382349600028-
dc.identifier.scopusid2-s2.0-84979686231-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryEnvironmental Sciences-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaEnvironmental Sciences & Ecology-
dc.type.docTypeArticle-
dc.subject.keywordPlusSELECTIVE HYDRODEOXYGENATION-
dc.subject.keywordPlusWATER/OIL INTERFACE-
dc.subject.keywordPlusBIOFUEL UPGRADE-
dc.subject.keywordPlusMETAL-CATALYSTS-
dc.subject.keywordPlusMODEL COMPOUNDS-
dc.subject.keywordPlusPYROLYSIS OIL-
dc.subject.keywordPlusAQUEOUS-PHASE-
dc.subject.keywordPlusHYDROGENOLYSIS-
dc.subject.keywordPlusBIOMASS-
dc.subject.keywordPlusFUELS-
dc.subject.keywordAuthorVanillin-
dc.subject.keywordAuthorRuthenium-
dc.subject.keywordAuthorAlumina-
dc.subject.keywordAuthorHydrodeoxygenation-
dc.subject.keywordAuthorCondensation-
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