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dc.contributor.authorWinoto, Haryo Pandu-
dc.contributor.authorAhn, Byoung Sung-
dc.contributor.authorJae, Jungho-
dc.date.accessioned2024-01-20T03:33:16Z-
dc.date.available2024-01-20T03:33:16Z-
dc.date.created2021-09-04-
dc.date.issued2016-08-25-
dc.identifier.issn1226-086X-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/123775-
dc.description.abstractA bifunctional Sn-Al-Beta zeolite which possesses isolated Lewis and Bronsted acid sites was prepared by a post-synthesis procedure and applied to the one-pot conversion of furfural to gamma-valerolactone (GVL), a value-added chemical. Sn-Al-Beta was capable of catalyzing a cascade of the transfer hydrogenation and hydrolysis of furfural to GVL by the interplay of Lewis and Bronsted acid sites. The degree of dealumination and the tin-incorporation method largely influence the acid properties of the catalyst and the catalyst selectivity. A high yield of GVL up to 60% was obtained with Sn-Al-Beta 7 (Si/Sn = 63 and Si/Al = 473) at 180 degrees C in 2-butanol. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE INC-
dc.subjectMEERWEIN-PONNDORF-VERLEY-
dc.subjectBAEYER-VILLIGER OXIDATIONS-
dc.subjectLEVULINIC ACID-
dc.subjectCELLULOSIC SUGARS-
dc.subjectSILICA-ALUMINA-
dc.subjectSITES-
dc.subjectCONVERSION-
dc.subjectISOMERIZATION-
dc.subjectREDUCTION-
dc.subjectBIOMASS-
dc.titleProduction of gamma-valerolactone from furfural by a single-step process using Sn-Al-Beta zeolites: Optimizing the catalyst acid properties and process conditions-
dc.typeArticle-
dc.identifier.doi10.1016/j.jiec.2016.06.007-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.40, pp.62 - 71-
dc.citation.titleJOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY-
dc.citation.volume40-
dc.citation.startPage62-
dc.citation.endPage71-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.description.journalRegisteredClasskci-
dc.identifier.kciidART002134928-
dc.identifier.wosid000381834800009-
dc.identifier.scopusid2-s2.0-84990913399-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryEngineering, Chemical-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaEngineering-
dc.type.docTypeReview-
dc.subject.keywordPlusMEERWEIN-PONNDORF-VERLEY-
dc.subject.keywordPlusBAEYER-VILLIGER OXIDATIONS-
dc.subject.keywordPlusLEVULINIC ACID-
dc.subject.keywordPlusCELLULOSIC SUGARS-
dc.subject.keywordPlusSILICA-ALUMINA-
dc.subject.keywordPlusSITES-
dc.subject.keywordPlusCONVERSION-
dc.subject.keywordPlusISOMERIZATION-
dc.subject.keywordPlusREDUCTION-
dc.subject.keywordPlusBIOMASS-
dc.subject.keywordAuthorBiomass conversion-
dc.subject.keywordAuthorBifunctional catalysis-
dc.subject.keywordAuthorSn-Al-Beta zeolites-
dc.subject.keywordAuthorFurfural-
dc.subject.keywordAuthorgamma-Valerolactone-
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