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dc.contributor.authorSchouwink, Pascal-
dc.contributor.authorDidelot, Emilie-
dc.contributor.authorLee, Young-Su-
dc.contributor.authorMazet, Thomas-
dc.contributor.authorCerny, Radovan-
dc.date.accessioned2024-01-20T04:31:35Z-
dc.date.available2024-01-20T04:31:35Z-
dc.date.created2021-09-04-
dc.date.issued2016-04-15-
dc.identifier.issn0925-8388-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/124168-
dc.description.abstractNovel Gd-based mixed-metal borohydrides A(n)Gd(BH4)(n+3) (A - K, Cs) are described in view of their magnetic cooling properties at cryogenic temperatures. The magnetic entropy changes correlate well with Gd3+ isolation and structural dimensionality in the discovered perovskite-type and other compounds. Crystal structures are resolved from Synchrotron X-ray Powder Diffraction and refined with solid state calculations. The isolated Gd-centres in five-fold coordination in K2Gd(BH4)(5), the first representative of a new structure type, lead to exceptionally high mass magnetic entropy change of 54.6 J kg(-1) K-1 at the maximum field change of 9 T. (C) 2016 Published by Elsevier B.V.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE SA-
dc.subjectMETAL BOROHYDRIDES-
dc.subjectDEMAGNETIZATION-
dc.subjectREFRIGERATION-
dc.subjectTEMPERATURES-
dc.subjectFRAMEWORK-
dc.subjectLI-
dc.titleStructural and magnetocaloric properties of novel gadolinium borohydrides-
dc.typeArticle-
dc.identifier.doi10.1016/j.jallcom.2015.12.182-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF ALLOYS AND COMPOUNDS, v.664, pp.378 - 384-
dc.citation.titleJOURNAL OF ALLOYS AND COMPOUNDS-
dc.citation.volume664-
dc.citation.startPage378-
dc.citation.endPage384-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000369061700049-
dc.identifier.scopusid2-s2.0-84954170759-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryMetallurgy & Metallurgical Engineering-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaMaterials Science-
dc.relation.journalResearchAreaMetallurgy & Metallurgical Engineering-
dc.type.docTypeArticle-
dc.subject.keywordPlusMETAL BOROHYDRIDES-
dc.subject.keywordPlusDEMAGNETIZATION-
dc.subject.keywordPlusREFRIGERATION-
dc.subject.keywordPlusTEMPERATURES-
dc.subject.keywordPlusFRAMEWORK-
dc.subject.keywordPlusLI-
dc.subject.keywordAuthorMagnetocaloric effect-
dc.subject.keywordAuthorGadolinium-
dc.subject.keywordAuthorBorohydride-
dc.subject.keywordAuthorPerovskite-
dc.subject.keywordAuthorPowder diffraction-
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