Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Schouwink, Pascal | - |
dc.contributor.author | Didelot, Emilie | - |
dc.contributor.author | Lee, Young-Su | - |
dc.contributor.author | Mazet, Thomas | - |
dc.contributor.author | Cerny, Radovan | - |
dc.date.accessioned | 2024-01-20T04:31:35Z | - |
dc.date.available | 2024-01-20T04:31:35Z | - |
dc.date.created | 2021-09-04 | - |
dc.date.issued | 2016-04-15 | - |
dc.identifier.issn | 0925-8388 | - |
dc.identifier.uri | https://pubs.kist.re.kr/handle/201004/124168 | - |
dc.description.abstract | Novel Gd-based mixed-metal borohydrides A(n)Gd(BH4)(n+3) (A - K, Cs) are described in view of their magnetic cooling properties at cryogenic temperatures. The magnetic entropy changes correlate well with Gd3+ isolation and structural dimensionality in the discovered perovskite-type and other compounds. Crystal structures are resolved from Synchrotron X-ray Powder Diffraction and refined with solid state calculations. The isolated Gd-centres in five-fold coordination in K2Gd(BH4)(5), the first representative of a new structure type, lead to exceptionally high mass magnetic entropy change of 54.6 J kg(-1) K-1 at the maximum field change of 9 T. (C) 2016 Published by Elsevier B.V. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | METAL BOROHYDRIDES | - |
dc.subject | DEMAGNETIZATION | - |
dc.subject | REFRIGERATION | - |
dc.subject | TEMPERATURES | - |
dc.subject | FRAMEWORK | - |
dc.subject | LI | - |
dc.title | Structural and magnetocaloric properties of novel gadolinium borohydrides | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.jallcom.2015.12.182 | - |
dc.description.journalClass | 1 | - |
dc.identifier.bibliographicCitation | JOURNAL OF ALLOYS AND COMPOUNDS, v.664, pp.378 - 384 | - |
dc.citation.title | JOURNAL OF ALLOYS AND COMPOUNDS | - |
dc.citation.volume | 664 | - |
dc.citation.startPage | 378 | - |
dc.citation.endPage | 384 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.identifier.wosid | 000369061700049 | - |
dc.identifier.scopusid | 2-s2.0-84954170759 | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Metallurgy & Metallurgical Engineering | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Metallurgy & Metallurgical Engineering | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | METAL BOROHYDRIDES | - |
dc.subject.keywordPlus | DEMAGNETIZATION | - |
dc.subject.keywordPlus | REFRIGERATION | - |
dc.subject.keywordPlus | TEMPERATURES | - |
dc.subject.keywordPlus | FRAMEWORK | - |
dc.subject.keywordPlus | LI | - |
dc.subject.keywordAuthor | Magnetocaloric effect | - |
dc.subject.keywordAuthor | Gadolinium | - |
dc.subject.keywordAuthor | Borohydride | - |
dc.subject.keywordAuthor | Perovskite | - |
dc.subject.keywordAuthor | Powder diffraction | - |
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