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dc.contributor.authorGermer, Wiebke-
dc.contributor.authorLeppin, Janine-
dc.contributor.authorKirchner, Carolina Nunes-
dc.contributor.authorCho, Hyeongrae-
dc.contributor.authorKim, Hyoung-Juhn-
dc.contributor.authorHenkensmeier, Dirk-
dc.contributor.authorLee, Kwan-Young-
dc.contributor.authorBrela, Mateusz-
dc.contributor.authorMichalak, Artur-
dc.contributor.authorDyck, Alexander-
dc.date.accessioned2024-01-20T07:04:06Z-
dc.date.available2024-01-20T07:04:06Z-
dc.date.created2021-09-05-
dc.date.issued2015-05-
dc.identifier.issn1438-7492-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/125510-
dc.description.abstractMethylated polybenzimidazole (O-PBI) based anion exchange membranes with a degree of methylation of ca. 78% were prepared in the iodide, chloride, carbonate, bicarbonate, and hydroxide form. Swelling in water showed a high anisotropy for chloride and carbonate exchangedmembranes and a strong plasticizing effect of water was confirmed by DMA. Carbonate and bicarbonate exchanged membranes revealed an ionomer peak around 0.25 angstrom(-1) in SAXS measurements suggesting a phase separated morphology. Theoretical DFT calculations were used to characterize geometries and electronic structure of polymer models and interactions with different anions, and to rationalize the water uptake/swelling behavior.-
dc.languageEnglish-
dc.publisherJohn Wiley & Sons Ltd.-
dc.titlePhase Separated Methylated Polybenzimidazole (O-PBI) Based Anion Exchange Membranes-
dc.typeArticle-
dc.identifier.doi10.1002/mame.201400345-
dc.description.journalClass1-
dc.identifier.bibliographicCitationMacromolecular Materials and Engineering, v.300, no.5, pp.497 - 509-
dc.citation.titleMacromolecular Materials and Engineering-
dc.citation.volume300-
dc.citation.number5-
dc.citation.startPage497-
dc.citation.endPage509-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000354215100002-
dc.identifier.scopusid2-s2.0-84928924601-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryPolymer Science-
dc.relation.journalResearchAreaMaterials Science-
dc.relation.journalResearchAreaPolymer Science-
dc.type.docTypeArticle-
dc.subject.keywordPlusFUEL-CELL APPLICATIONS-
dc.subject.keywordPlusPOLYMERIZED IONIC LIQUIDS-
dc.subject.keywordPlusFOCK-SLATER CALCULATIONS-
dc.subject.keywordPlusTRANSITION-STATE METHOD-
dc.subject.keywordPlusAQUEOUS-SOLUTION-
dc.subject.keywordPlusHYDRATION STRUCTURE-
dc.subject.keywordPlusIMPLICIT SOLVATION-
dc.subject.keywordPlusCONDUCTING POLYMER-
dc.subject.keywordPlusFREE-ENERGIES-
dc.subject.keywordPlusSTABILITY-
dc.subject.keywordAuthoranion exchange membranes-
dc.subject.keywordAuthorcomputer modeling-
dc.subject.keywordAuthorion exchange-
dc.subject.keywordAuthormechanical properties-
dc.subject.keywordAuthorthermal properties-
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