Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Lee, Seulyi | - |
dc.contributor.author | Jeon, Hyeonyeol | - |
dc.contributor.author | Jang, Mi | - |
dc.contributor.author | Baek, Kyung-Youl | - |
dc.contributor.author | Yang, Hoichang | - |
dc.date.accessioned | 2024-01-20T08:01:49Z | - |
dc.date.available | 2024-01-20T08:01:49Z | - |
dc.date.created | 2022-01-25 | - |
dc.date.issued | 2015-01 | - |
dc.identifier.issn | 1944-8244 | - |
dc.identifier.uri | https://pubs.kist.re.kr/handle/201004/125886 | - |
dc.description.abstract | A highly pi-conjugated nanofibrillar network of poly(3-hexyl thiophene) (P3HT) embedded in polydimethylsiloxane (PDMS) elastomer films on SiO2 dielectrics was facilely developed via solution-blending of an ultrasound-assisted dilute P3HT solution with a PDMS precursor followed by spin-casting and curing. In contrast, simple blending without ultrasonication against the dilute P3HT solution yielded large agglomerates in cast films owing to a great difference in solubility parameter (delta) values (P3HT = 9.5 cal(1/2) cm(-3/2), PDMS = 7.3 cal(1/2) cm(-3/2)). In the ultrasound-assisted 0.1 vol % P3HT solutions, the pi-conjugated polymer could develop crystalline nanofibrils surrounded by nonpolar hexyl side chains with the same delta value as that of PDMS, yielding homogeneously dispersed 10 wt % loaded P3HT/PDMS blend films. Spun-cast P3HT/PDMS blend films could yield high electrical properties in organic field-effect transistor, including mobilities of up to 0.045 cm2 V-1 s(-1) and on/off current ratios of >5 x 10(5), as well as excellent environmental stability owing to the outer PDMS layer. | - |
dc.language | English | - |
dc.publisher | American Chemical Society | - |
dc.title | Tunable Solubility Parameter of Poly(3-hexyl thiophene) with Hydrophobic Side-Chains to Achieve Rubbery Conjugated Films | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/am507512m | - |
dc.description.journalClass | 1 | - |
dc.identifier.bibliographicCitation | ACS Applied Materials & Interfaces, v.7, no.2, pp.1290 - 1297 | - |
dc.citation.title | ACS Applied Materials & Interfaces | - |
dc.citation.volume | 7 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 1290 | - |
dc.citation.endPage | 1297 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.identifier.wosid | 000348332700031 | - |
dc.identifier.scopusid | 2-s2.0-84921512283 | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | FIELD-EFFECT MOBILITY | - |
dc.subject.keywordPlus | THIN-FILMS | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE | - |
dc.subject.keywordPlus | TRANSISTORS | - |
dc.subject.keywordPlus | POLYMER | - |
dc.subject.keywordPlus | MORPHOLOGY | - |
dc.subject.keywordPlus | CRYSTALLIZATION | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | INTERFACE | - |
dc.subject.keywordPlus | CRYSTALS | - |
dc.subject.keywordAuthor | ultrasonification | - |
dc.subject.keywordAuthor | solubility | - |
dc.subject.keywordAuthor | parameter | - |
dc.subject.keywordAuthor | miscibility | - |
dc.subject.keywordAuthor | directed self-assembly | - |
dc.subject.keywordAuthor | poly(3-hexyl thiophene) | - |
dc.subject.keywordAuthor | organic field-effect transistor | - |
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