터널 내 기체 및 입자상 다환방향족탄화수소(PAH) 분포 특성

Abstract

Twenty four individual polycyclic aromatic hydrocarbon (PAH) compounds both in gas- and particle-phase werequantified in three tunnels (Namsan Tunnel 3, Jeongneung Tunnel, Bukak Tunnel) to characterize vehiculate emissionof PAHs. Gas phase PAHs were dominant in tunnels which consisted of 85% of total PAHs concentrations. Naphthalene and 2-methyl naphthalene were the most abundant gas phase PAH compounds, while the concentrationsof fluoranthene and pyrene were highest in the particle phase. Most (96%) of the gas phase PAH compoundsconsisted of two- and three-aromatic rings whereas most of the particle phase PAHs were in four and five-rings (67%)in tunnels. Average BaP-eq concentrations of PAHs in the particle phase (20.8±11.6 ng m-3) was about twenty foldhigher than that in the gas phase (1.6±0.6 ng m-3). It means that the particle phase PAHs has more adverse healtheffect than the gas phase PAHs even though the concentrations of the particle phase PAHs were lower than those ofthe gas phase PAHs. Compared to previous studies reporting diagnostic ratios for specific PAH compounds, the profileof individual PAH compounds measured in this study reflected well for the vehiculate emissions. We reported,for the first time, on the results of the profile of individual PAH compounds measured in tunnels for both gas andparticle phases.