Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Kim, Jin Hoon | - |
dc.contributor.author | Bae, Jeong Mi | - |
dc.contributor.author | Lee, Hong Gyu | - |
dc.contributor.author | Kim, Nack Joo | - |
dc.contributor.author | Jung, Kwang-Deog | - |
dc.contributor.author | Kim, Cheal | - |
dc.contributor.author | Kim, Sung-Jin | - |
dc.contributor.author | Kim, Youngmee | - |
dc.date.accessioned | 2024-01-20T14:30:14Z | - |
dc.date.available | 2024-01-20T14:30:14Z | - |
dc.date.created | 2021-09-05 | - |
dc.date.issued | 2012-08 | - |
dc.identifier.issn | 1387-7003 | - |
dc.identifier.uri | https://pubs.kist.re.kr/handle/201004/129028 | - |
dc.description.abstract | We showed a systematic investigation on the coordination polymers assembled from metal(11) benzoates and bpe ligands. 1-Mn and 5-Zn show ladder-type double chains, 2-Co does a simple linear chain, 3-Ni does a two-dimensional sheet, 4-Cu does a chain containing paddle-wheel dinuclear units, 6-Cd does a thick one-dimensional structure containing newly generated [2 + 2] addition product 4pycb ligands. In addition, light-induced [2 + 2] addition reaction occurs for CdII ions, and C=C double bonds that were aligned for photo-induced [2 + 2] cycloaddition in ZnII ion undergo the photo-induced cycloaddition by UV lamp. Luminescences of compounds 3 and 4 showed strong emissions, while relatively weak luminescences were observed for 1 and 2. Moreover, 4-Cu and 1-Mn have shown efficient catalytic reactivities, while 2-Co, 3-Ni and 6-Cd have displayed a very slow conversion. The reactivities of the compounds used in this study are in the order of 5-Zn>4-Cu>1-Mn>2-Co >> 3-Ni>6-Cd. (C) 2012 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ELSEVIER | - |
dc.subject | ZINC(II)-BENZOATE COORDINATION-COMPLEXES | - |
dc.subject | CATALYTIC-ACTIVITIES | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | SUPRAMOLECULAR ISOMERISM | - |
dc.subject | ZN(II) COMPOUNDS | - |
dc.subject | SOLVENT | - |
dc.subject | TRANSESTERIFICATION | - |
dc.subject | PHOTODIMERIZATION | - |
dc.subject | CONSTRUCTION | - |
dc.subject | MOLECULES | - |
dc.title | Metal-directed assembly of metal(II) benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) with 1,2-bis(4-pyridyl)ethene: Light- and photo-induced [2+2] cycloaddition | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.inoche.2012.05.011 | - |
dc.description.journalClass | 1 | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY COMMUNICATIONS, v.22, pp.1 - 5 | - |
dc.citation.title | INORGANIC CHEMISTRY COMMUNICATIONS | - |
dc.citation.volume | 22 | - |
dc.citation.startPage | 1 | - |
dc.citation.endPage | 5 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.identifier.wosid | 000307133800001 | - |
dc.identifier.scopusid | 2-s2.0-84863307123 | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | ZINC(II)-BENZOATE COORDINATION-COMPLEXES | - |
dc.subject.keywordPlus | CATALYTIC-ACTIVITIES | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | SUPRAMOLECULAR ISOMERISM | - |
dc.subject.keywordPlus | ZN(II) COMPOUNDS | - |
dc.subject.keywordPlus | SOLVENT | - |
dc.subject.keywordPlus | TRANSESTERIFICATION | - |
dc.subject.keywordPlus | PHOTODIMERIZATION | - |
dc.subject.keywordPlus | CONSTRUCTION | - |
dc.subject.keywordPlus | MOLECULES | - |
dc.subject.keywordAuthor | 1,2-bis(4-pyridyl)ethene | - |
dc.subject.keywordAuthor | [2+2] cycloaddition | - |
dc.subject.keywordAuthor | Coordination polymers | - |
dc.subject.keywordAuthor | Transesterification | - |
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