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dc.contributor.authorKim, Byungsook-
dc.contributor.authorLee, Miseon-
dc.contributor.authorKim, Mi Jung-
dc.contributor.authorLee, Hyunjoo-
dc.contributor.authorKim, Sanghee-
dc.contributor.authorKim, Deukjoon-
dc.contributor.authorKoh, Minseob-
dc.contributor.authorPark, Seung Bum-
dc.contributor.authorShin, Kye Jung-
dc.date.accessioned2024-01-20T22:04:56Z-
dc.date.available2024-01-20T22:04:56Z-
dc.date.created2021-09-03-
dc.date.issued2008-12-10-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/132882-
dc.description.abstractThe first asymmetric total synthesis of (-)-laurefucin (1), a unique C-15 acetogenin with a 2,8-dioxabicyclo[5.2.1]decane skeleton, has been accomplished in nine steps in 31% overall yield from known oxocene 10. Highlights of the highly stereoselective synthesis include a novel organoselenium-mediated biomimetic hydroxyetherification.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectMEDIUM RING ETHERS-
dc.subjectLAURENCIA-PINNATIFIDA-
dc.subjectCARBONYL-COMPOUNDS-
dc.subjectC-15 ACETOGENINS-
dc.subject(+)-LAURENCIN-
dc.subjectMETABOLITES-
dc.subjectABSOLUTE-
dc.subjectCONFIGURATION-
dc.subjectCONSTRUCTION-
dc.subjectCYCLIZATIONS-
dc.titleBiomimetic Asymmetric Total Synthesis of (-)-Laurefucin via an Organoselenium-Mediated Intramolecular Hydroxyetherification-
dc.typeArticle-
dc.identifier.doi10.1021/ja806304s-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.130, no.49, pp.16807 - 16811-
dc.citation.titleJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.citation.volume130-
dc.citation.number49-
dc.citation.startPage16807-
dc.citation.endPage16811-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000263320200071-
dc.identifier.scopusid2-s2.0-57549083399-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusMEDIUM RING ETHERS-
dc.subject.keywordPlusLAURENCIA-PINNATIFIDA-
dc.subject.keywordPlusCARBONYL-COMPOUNDS-
dc.subject.keywordPlusC-15 ACETOGENINS-
dc.subject.keywordPlus(+)-LAURENCIN-
dc.subject.keywordPlusMETABOLITES-
dc.subject.keywordPlusABSOLUTE-
dc.subject.keywordPlusCONFIGURATION-
dc.subject.keywordPlusCONSTRUCTION-
dc.subject.keywordPlusCYCLIZATIONS-
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