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dc.contributor.authorMin, Sun-Joon-
dc.contributor.authorJones, Gavin O.-
dc.contributor.authorHouk, K. N.-
dc.contributor.authorDanishefsky, Samuel J.-
dc.date.accessioned2024-01-21T00:33:50Z-
dc.date.available2024-01-21T00:33:50Z-
dc.date.created2021-08-31-
dc.date.issued2007-08-22-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/134189-
dc.description.abstractEthynyl substituents were used to direct a highly exoselective creation of quaternary carbon centers in Diels-Alder cycloaddition reactions involving activated alpha-alkynyl dienophiles. The origins of electronic activation and the high stereoselectivities of these reactions were investigated by the B3LYP density functional method.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectDIELS-ALDER REACTIONS-
dc.subjectSECONDARY ORBITAL INTERACTIONS-
dc.subjectVIBRATIONAL ABSORPTION-
dc.subjectSTEREOGENIC CENTERS-
dc.subjectPAECILOMYCINE-A-
dc.subjectACIDITY TRENDS-
dc.subjectDENSITY-
dc.subjectSTEREOCENTERS-
dc.titleCreating quaternary centers with high exo stereoselectivity using activated alpha-alkynyl dienophiles-
dc.typeArticle-
dc.identifier.doi10.1021/ja073528d-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.129, no.33, pp.10078 - +-
dc.citation.titleJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.citation.volume129-
dc.citation.number33-
dc.citation.startPage10078-
dc.citation.endPage+-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000248896400017-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusDIELS-ALDER REACTIONS-
dc.subject.keywordPlusSECONDARY ORBITAL INTERACTIONS-
dc.subject.keywordPlusVIBRATIONAL ABSORPTION-
dc.subject.keywordPlusSTEREOGENIC CENTERS-
dc.subject.keywordPlusPAECILOMYCINE-A-
dc.subject.keywordPlusACIDITY TRENDS-
dc.subject.keywordPlusDENSITY-
dc.subject.keywordPlusSTEREOCENTERS-
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