Novel isothiocyanate transposition in 2-alkyliminothiazoles: a simple solution for regiochemical problem

Authors
Shin, DongyunLee, JihoonNam, Kee DalHahn, Hoh-Gyu
Issue Date
2007-04-23
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
TETRAHEDRON LETTERS, v.48, no.17, pp.3089 - 3092
Abstract
Novel alkyl/aryl transposition in the reaction of 2-iminothiazoles with alkyl/aryl isothiocyanates was found out, and the reaction was very easy to handle and gave good to excellent chemical yields. Moreover, transposition reaction provided a simple but excellent solution for regiochemical problems in 2-iminothiazole synthesis. (c) 2007 Elsevier Ltd. All rights reserved.
Keywords
DISCOVERY; DISCOVERY; 2-iminothiazole; isothiocyanate; transposition; regiochemistry
ISSN
0040-4039
URI
https://pubs.kist.re.kr/handle/201004/134444
DOI
10.1016/j.tetlet.2007.02.084
Appears in Collections:
KIST Article > 2007
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