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dc.contributor.authorShim, Jae-Hyeok-
dc.contributor.authorLee, Gil-Jae-
dc.contributor.authorCho, Young Whan-
dc.date.accessioned2024-01-21T02:34:07Z-
dc.date.available2024-01-21T02:34:07Z-
dc.date.created2021-09-01-
dc.date.issued2006-08-10-
dc.identifier.issn0925-8388-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/135246-
dc.description.abstractThe reaction between TiCl3 and LbAlH(6) was investigated to understand reaction products in Ti-catalyzed Li3AlH6 using mechanical milling and thermodynamic calculation. As reaction products, LiCl, TiAl3 and TiH2 are observed by X-ray powder diffraction, which is in agreement with the results of thermodynamic calculation. TiAl3 forms in an L1(2) structure rather than an equilibrium D0(22) structure during milling. It is predicted that the mole fraction of TiAl3 increases and that of TiH2 decreases as temperature increases during milling. Differential scanning calorimetry confirms that TiAl3 acts as a dehydrogenation catalyst in Li3AlH6. (c) 2005 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE SA-
dc.subjectREVERSIBLE HYDROGEN STORAGE-
dc.subjectLIALH4-
dc.subjectTRANSFORMATIONS-
dc.subjectSTABILITY-
dc.titleReaction products between TiCl3 catalyst and Li3AlH6 during mechanical mixing-
dc.typeArticle-
dc.identifier.doi10.1016/j.jallcom.2005.07.079-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF ALLOYS AND COMPOUNDS, v.419, no.1-2, pp.176 - 179-
dc.citation.titleJOURNAL OF ALLOYS AND COMPOUNDS-
dc.citation.volume419-
dc.citation.number1-2-
dc.citation.startPage176-
dc.citation.endPage179-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000238991900031-
dc.identifier.scopusid2-s2.0-33745267054-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryMetallurgy & Metallurgical Engineering-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaMaterials Science-
dc.relation.journalResearchAreaMetallurgy & Metallurgical Engineering-
dc.type.docTypeArticle-
dc.subject.keywordPlusREVERSIBLE HYDROGEN STORAGE-
dc.subject.keywordPlusLIALH4-
dc.subject.keywordPlusTRANSFORMATIONS-
dc.subject.keywordPlusSTABILITY-
dc.subject.keywordAuthorenergy storage materials-
dc.subject.keywordAuthormechanochemical synthesis-
dc.subject.keywordAuthorX-ray diffraction-
dc.subject.keywordAuthorthermal analysis-
dc.subject.keywordAuthorhydrogen storage materials-
dc.subject.keywordAuthorcatalyst-
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