Extension of the surfactant bridge model for the electrorheological effects of surfactant-activated suspensions

Abstract

Surfactants influence the electrorheological (ER) response in two ways. At low surfactant concentrations, they enhance the ER response by enhancing the particle polarizability; at high concentrations, the response degrades (nonlinear ER response). The nonlinear ER behavior arises from the formation of surfactant bridges between the particles at high surfactant concentrations. A surfactant bridge-model was introduced to explain the nonlinear behavior (tau(0) proportional to E-n, n approximate to 1) of surfactant-activated ER suspensions when surfactant bridges were formed between the particles. Here, the surfactant bridge model is extended for the prediction of both the linear and nonlinear ER behaviors of surfactant-activated ER suspensions over the low and high surfactant concentrations (for Brij 30, from 0 to 7 wt%), regardless of the formation of surfactant bridges between the particles. For 20 wt% neutral alumina suspensions in silicone oil activated by Brij 30, the predicted ER behaviors show almost the same Brij 30 concentration and electric field strength dependence. It predicts the linear E-2 dependence of the ER response at low surfactant concentrations and the nonlinear ER behavior at high surfactant concentrations. Also, the estimated yield stresses show fairly good agreement with the experimental data. (C) 2003 Elsevier Inc. All rights reserved.