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dc.contributor.authorLim, CW-
dc.contributor.authorLee, S-
dc.date.accessioned2024-01-21T13:41:54Z-
dc.date.available2024-01-21T13:41:54Z-
dc.date.created2021-09-05-
dc.date.issued2000-07-14-
dc.identifier.issn0040-4020-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/141231-
dc.description.abstractA series of novel C-2-symmetric bisphosphine ligands derived from DPPBA and C-2-symmetric 1,1'-binaphthyldiamines has been synthesized. In palladium catalyzed desymmetrization of meso cyclic carbamates, the enantioselectivity and the stereochemistry of the major enantiomers are largely affected by the substitution position of DPPBA moiety on the 1,1'-binaphthyl chiral scaffold. (C) 2000 Elsevier Science Ltd. All rights reserved.-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectASYMMETRIC ALLYLIC SUBSTITUTION-
dc.subjectCYCLIC BORATE ESTER-
dc.subjectBINAPHTHOL DERIVATIVES-
dc.subjectARYL BROMIDES-
dc.subjectENANTIOSELECTIVE SYNTHESIS-
dc.subjectREDUCTIVE ELIMINATION-
dc.subjectMOLECULAR RECOGNITION-
dc.subjectCOUPLING REACTIONS-
dc.subjectSECONDARY-AMINES-
dc.subjectFACILE SYNTHESIS-
dc.titleC-2-symmetric bisphosphine ligands derived from 1,1 '-binaphthyldiamines and diphenylphosphinobenzoic acid for palladium catalyzed desymmetrizations-
dc.typeArticle-
dc.identifier.doi10.1016/S0040-4020(00)00420-8-
dc.description.journalClass1-
dc.identifier.bibliographicCitationTETRAHEDRON, v.56, no.29, pp.5131 - 5136-
dc.citation.titleTETRAHEDRON-
dc.citation.volume56-
dc.citation.number29-
dc.citation.startPage5131-
dc.citation.endPage5136-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000088199900009-
dc.identifier.scopusid2-s2.0-0008639668-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusASYMMETRIC ALLYLIC SUBSTITUTION-
dc.subject.keywordPlusCYCLIC BORATE ESTER-
dc.subject.keywordPlusBINAPHTHOL DERIVATIVES-
dc.subject.keywordPlusARYL BROMIDES-
dc.subject.keywordPlusENANTIOSELECTIVE SYNTHESIS-
dc.subject.keywordPlusREDUCTIVE ELIMINATION-
dc.subject.keywordPlusMOLECULAR RECOGNITION-
dc.subject.keywordPlusCOUPLING REACTIONS-
dc.subject.keywordPlusSECONDARY-AMINES-
dc.subject.keywordPlusFACILE SYNTHESIS-
dc.subject.keywordAuthorC-2-symmetric-
dc.subject.keywordAuthorbinaphthylbisphosphine-
dc.subject.keywordAuthorpalladium-
dc.subject.keywordAuthordesymmetrizations-
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