Vapor-liquid equilibrium measurements for binary mixtures containing 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea)

Abstract

Isothermal vapor-liquid equilibrium data for two binary mixtures of alternative refrigerants were determined by using an apparatus applying recirculating vapor and liquid. The difluoromethane (HFC-32) + 1,1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) and 1,1,1,2-tetranuoroethane (HFC-134a) + 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) systems were studied at 298.15 and 312.65 K. The pressure and vapor and liquid compositions were measured at each temperature. The experimental data were correlated with the Peng-Robinson equation of state using the van der Waals one-fluid mixing rule. Calculated results show that this equation yields good agreement with the experimental data.