Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Moon, Subin | - |
dc.contributor.author | Park, Young Sun | - |
dc.contributor.author | Lee, Hyungsoo | - |
dc.contributor.author | Jeong, Wooyong | - |
dc.contributor.author | Kwon, Eunji | - |
dc.contributor.author | Lee, Jeongyoub | - |
dc.contributor.author | Yun, Juwon | - |
dc.contributor.author | Lee, Soobin | - |
dc.contributor.author | Kim, Jun Hwan | - |
dc.contributor.author | Yu, Seungho | - |
dc.contributor.author | Moon, Jooho | - |
dc.date.accessioned | 2024-07-18T08:00:54Z | - |
dc.date.available | 2024-07-18T08:00:54Z | - |
dc.date.created | 2024-07-18 | - |
dc.date.issued | 2024-08 | - |
dc.identifier.issn | 1754-5692 | - |
dc.identifier.uri | https://pubs.kist.re.kr/handle/201004/150280 | - |
dc.description.abstract | Hydrogen peroxide (H2O2) represents a valuable chemical compound and promising energy source due to its high energy density, comparable with that of compressed H-2. However, its production predominantly relies on an energy-intensive process. In this study, we present an efficient strategy for producing H2O2 through a photoelectrochemical (PEC) approach, which involves a 2e(-)-mediated oxygen reduction reaction, integrating Mo-anchored MoOx with a Cu3BiS3-based photocathode. The MoOx-supported Mo improves the adsorption strength of peroxide species and facilitates electron transport, resulting in outstanding activity toward H2O2 production. Consequently, the resulting Cu3BiS3-based photocathode demonstrates significantly enhanced performance, achieving a photocurrent density of 5.21 mA cm(-2) at 0.35 V versus the reversible hydrogen electrode (RHE), a high onset potential of 0.9 V-RHE, and 97% selectivity toward H2O2. Additionally, we successfully implemented an unassisted PEC-PEC coplanar system by coupling a Cu3BiS3-based photocathode with a perovskite-based photoanode, achieving a solar-to-chemical conversion efficiency of 1.46%. | - |
dc.language | English | - |
dc.publisher | Royal Society of Chemistry | - |
dc.title | Unassisted photoelectrochemical hydrogen peroxide production over MoOx-supported Mo on a Cu3BiS3 photocathode | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/d4ee00741g | - |
dc.description.journalClass | 1 | - |
dc.identifier.bibliographicCitation | Energy & Environmental Science, v.17, no.15, pp.5588 - 5600 | - |
dc.citation.title | Energy & Environmental Science | - |
dc.citation.volume | 17 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 5588 | - |
dc.citation.endPage | 5600 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.identifier.wosid | 001265393000001 | - |
dc.identifier.scopusid | 2-s2.0-85198047147 | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.relation.journalWebOfScienceCategory | Environmental Sciences | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalResearchArea | Environmental Sciences & Ecology | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | OXYGEN REDUCTION REACTION | - |
dc.subject.keywordPlus | H2O2 | - |
dc.subject.keywordPlus | INTERFACE | - |
dc.subject.keywordPlus | SURFACE | - |
dc.subject.keywordPlus | CO | - |
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