Exploring pyrolusite β-MnO2 as a robust support for noble metal catalysts in proton exchange membrane water electrolysis

Abstract

Proton exchange membrane water electrolysis (PEMWE) represents a promising avenue for producing hydrogen sustainably. Nonetheless, its widespread adoption encounters hurdles owing to the sluggishness of the oxygen evolution reaction (OER) and the expensive noble metal catalysts, particularly iridium (Ir). Our investigation addresses these challenges by examining pyrolusite beta-MnO2 as a robust substrate for noble metal catalysts, including iridium (Ir) and ruthenium (Ru), within PEMWE systems. We illustrate that nanostructured beta-MnO2 effectively supports Ir and Ru catalysts, resulting in significantly improved catalytic activity for acidic OER compared to conventional IrO2 catalysts. The morphology shows nanorod structures with thicknesses ranging of 30-60 nm. The catalytic activity exhibits a lower overpotential of 215 mV and a higher Ir mass activity of 2268.7 A center dot g(Ir)(-1). The catalyst also exhibits lower Tafel slope value (37.82 mV/dec) and higher reaction kinetics. The catalyst also shows durability for the 12h under corrosive acidic OER conditions. The enhancements in performance can be attributed to the distinctive nanostructure of the Mn1-xTixO2 (MTO) support, which facilitates the even distribution of Ir and Ru catalysts. Additionally, the incorporation of titanium in pyrolusite beta-MnO2 enhances the electrochemical durability of the MTO support under challenging acidic OER conditions.