Anionic synthesis of macromonomer carrying amino group using diphenylethylene derivative

Abstract

Non-homopolymerizable macromonomer carrying amino-functional group at the chain-end was successfully synthesized through the chain-end functionalization methodology of living polymers using 1-[4-[N,N-bis(trimethylsilyl) amino]phenyl]-1-phenylethylene (ADPE) and 1,3-bis(phenylethenyl)benzene (MDDPE).