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dc.contributor.authorMoon, Hyunyoung-
dc.contributor.authorYoon, Hojong-
dc.contributor.authorLim, Changjin-
dc.contributor.authorJang, Jaebong-
dc.contributor.authorYi, Jong-Jae-
dc.contributor.authorLee, Jae Kyun-
dc.contributor.authorLee, Jeeyeon-
dc.contributor.authorNa, Younghwa-
dc.contributor.authorSon, Woo Sung-
dc.contributor.authorKim, Seok-Ho-
dc.contributor.authorSuh, Young-Ger-
dc.date.accessioned2024-01-19T22:01:58Z-
dc.date.available2024-01-19T22:01:58Z-
dc.date.created2021-09-03-
dc.date.issued2018-09-
dc.identifier.issn1420-3049-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/120992-
dc.description.abstractThe versatile synthesis of (-)-6-desmethyl-fluvirucinine A(1) was accomplished at a 24% overall yield through a thirteen-step process from a known vinylpiperidine. The key part involved the elaboration of the distal stereocenters and a macrolactam skeleton via conformationally-induced diastereocontrol and the iterative aza-Claisen rearrangements of lactam precursors.-
dc.languageEnglish-
dc.publisherMDPI-
dc.subjectINFLUENZA-A VIRUS-
dc.subjectENANTIOSELECTIVE TOTAL-SYNTHESIS-
dc.subjectAZA-CLAISEN REARRANGEMENT-
dc.subjectN,O-ACETAL TMS ETHER-
dc.subjectANTHELMINTIC MACROLACTAMS-
dc.subjectVERSATILE CONVERSION-
dc.subjectSCH 38516-
dc.subjectFLUVIRUCIN-B2-
dc.subjectALKALOIDS-
dc.subjectAGLYCON-
dc.titleAsymmetric Synthesis of (-)-6-Desmethyl-Fluvirucinine A(1) via Conformationally-Controlled Diastereoselective Lactam-Ring Expansions-
dc.typeArticle-
dc.identifier.doi10.3390/molecules23092351-
dc.description.journalClass1-
dc.identifier.bibliographicCitationMOLECULES, v.23, no.9-
dc.citation.titleMOLECULES-
dc.citation.volume23-
dc.citation.number9-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000447365100262-
dc.identifier.scopusid2-s2.0-85053621093-
dc.relation.journalWebOfScienceCategoryBiochemistry & Molecular Biology-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalResearchAreaBiochemistry & Molecular Biology-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusINFLUENZA-A VIRUS-
dc.subject.keywordPlusENANTIOSELECTIVE TOTAL-SYNTHESIS-
dc.subject.keywordPlusAZA-CLAISEN REARRANGEMENT-
dc.subject.keywordPlusN,O-ACETAL TMS ETHER-
dc.subject.keywordPlusANTHELMINTIC MACROLACTAMS-
dc.subject.keywordPlusVERSATILE CONVERSION-
dc.subject.keywordPlusSCH 38516-
dc.subject.keywordPlusFLUVIRUCIN-B2-
dc.subject.keywordPlusALKALOIDS-
dc.subject.keywordPlusAGLYCON-
dc.subject.keywordAuthorfluvirucinine-
dc.subject.keywordAuthoraza-Claisen rearrangement-
dc.subject.keywordAuthoramidoalkylation-
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