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POSS-Based Covalent Networks: Supporting and Stabilizing Pd for Heck Reaction in Aqueous Media

Authors: Arsalani, Nasser; Akbari, Ali; Amini, Mojtaba; Jabbari, Esmaiel; Gautam, Sanjeev; Chae, Keun Hwa

Issue Date: 2017-04

Publisher: SPRINGER

Citation: CATALYSIS LETTERS, v.147, no.4, pp.1086 - 1094

Abstract: Palladium nanoparticles supported on Incompletely Condensed Polyhedral Oligomeric Silsesquioxane (IC-POSS) based poly (Acrylamide-co-Hydroxy ethyl methacrylate) as a novel nanohybrid catalyst were synthesized and characterized. This catalyst was found to be an efficient and reusable heterogeneous catalyst for the Heck reaction using water as the solvent in the absence of a phosphine ligand and phase transfer catalyst.

Keywords: POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; CATALYTIC-ACTIVITY; HYBRID NANOCOMPOSITES; MIZOROKI-HECK; SCHIFF-BASE; NANOPARTICLES; WATER; SONOGASHIRA; EPOXIDATION; COUPLINGS; POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; CATALYTIC-ACTIVITY; HYBRID NANOCOMPOSITES; MIZOROKI-HECK; SCHIFF-BASE; NANOPARTICLES; WATER; SONOGASHIRA; EPOXIDATION; COUPLINGS; Polyhedral Oligomeric Silsesquioxane; Hybrid copolymer; Heck reaction; And radical polymerization

ISSN: 1011-372X

URI: https://pubs.kist.re.kr/handle/201004/122925

DOI: 10.1007/s10562-016-1954-8

Appears in Collections:: KIST Article > 2017

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